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Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws.
The Aufbau Principle and Hund's Rule
To determine the electron configuration for any particular atom, we can build the structures in the order of atomic numbers. Beginning with hydrogen, and continuing across the periods of the periodic table, we add one proton at a time to the nucleus and one electron to the proper subshell until we have described the electron configurations of all the elements. This procedure is called the aufbau principle, from the German word aufbau (“to build up”). Each added electron occupies the subshell of...
Noble Gases
The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
Ideal Gas Equation
The ideal gas equation is an equation of state that relates the state variables pressure, volume, temperature, and the number of moles of a hypothetical gas. This equation is a combination of four empirical laws, namely Boyle’s Law, Charles’s Law, Avogadro’s Law, and Gay-Lussac’s Law. When the proportionalities of the above four empirical laws are combined, it results in a single proportionality constant known as the universal gas constant.
Physical Principles Governing Gas Exchange
Gas behavior plays a vital role in understanding bodily processes such as external and internal respiration. External respiration involves the diffusion of oxygen into the blood and carbon dioxide out of it in the lungs. In contrast, internal respiration happens in body tissues, where these gases move in opposite directions.
Gas Laws Governing Respiration
The behavior of gases is guided by Dalton's Law of partial pressures and Henry's Law.
Dalton's Law asserts that the total pressure exerted by...
Gas Laws Governing Respiration
The behavior of gases is guided by Dalton's Law of partial pressures and Henry's Law.
Dalton's Law asserts that the total pressure exerted by...
Gas Solubility
Gas solubility in liquids forms liquid-gas solutions, such as soft drinks, where carbon dioxide is dissolved in water, and the ocean, where the solubility of oxygen and carbon dioxide supports marine life. The ability of oceans to dissolve gases impacts weather conditions in the troposphere.However, gas-liquid interactions vary. For instance, hydrogen chloride gas is highly soluble in water, while oxygen's solubility is much lower. Because these solutions are non-ideal, Raoult’s law, which...


