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Updated: Jul 17, 2026

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Published on: September 20, 2016
Mineral induced phosphorylation of glycolate ion--a metaphor in chemical evolution
1Department of Chemistry, University of Wisconsin-Parkside, Kenosha 53141, USA.
Abstract:
Bilateral surface-active minerals with excess positive charge concentrate glycolate and trimetaphosphate ion from l0(-3) m aqueous solution to half-saturation of the internal surface sites, and induce phosphorylation of glycolate ion in the mineral with trimetaphosphate, sorbed from l0(-2) m solution. By utilizing reactants from dilute solution at near-neutral pH, and eliminating the need for participating organic nitrogen compounds, the reaction comprises several elements considered necessary for geochemical realism in models for molecular evolution.
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