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The synthesis of prostaglandin analogs containing hydroxycyclohexenyl rings
Prostaglandins
|April 1, 1975
Abstract:
The synthesis of prostaglandin analogs incorporating the 3-hydroxycyclohexenyl moiety in place of the natural C13-C20 side-chain has been accomplished via copper-assisted conjugate addition of the cycloalkenyllithium 2 to the cyclopentenous intermediates 4, 7 and 10.