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Bis(N-octylsalicylideniminato-N,O)copper(II)
1Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
Acta Crystallographica. Section C, Crystal Structure Communications
|October 16, 2001
Summary
This study details the crystal structure of a copper(II) complex with Schiff base ligands. The copper ion exhibits a parallelogram coordination geometry, highlighting its specific electronic and structural properties.
Area of Science:
- Coordination Chemistry
- Crystallography
- Materials Science
Background:
- Schiff base ligands are versatile in coordination chemistry.
- Copper(II) complexes are of interest due to their diverse applications.
Purpose of the Study:
- To elucidate the crystal structure and coordination geometry of a novel copper(II) complex.
- To analyze the bonding interactions within the complex.
Main Methods:
- Single crystal X-ray diffraction was used to determine the molecular structure.
- Analysis of bond lengths and angles provided insights into coordination geometry.
Main Results:
- The copper(II) cation is located on a center of symmetry.
- The coordination geometry is a parallelogram, defined by an N(2)O(2) donor set.
- Specific Cu-N (2.009 Å) and Cu-O (1.888 Å) bond distances were measured.
Conclusions:
- The synthesized compound features a well-defined coordination environment around the copper(II) ion.
- The structural data provides a foundation for understanding the properties of related Schiff base copper complexes.