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Updated: Jul 30, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
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Published on: February 11, 2012

A(5)TaAs(4)Tl(2) (A = Rb, K). Transition-Metal Zintl Phases with a Novel Complex Ion: Synthesis, Structure, and

DaPing Huang1, John D. Corbett

  • 1Ames Laboratory-DOE(1) and Department of Chemistry, Iowa State University, Ames, Iowa 50011.

Inorganic Chemistry
|October 24, 2001
PubMed
Summary

The rubidium-thallium-arsenic (Rb-Tl-As) system forms a novel compound, Rb(5)TaAs(4)Tl(2), through reactions with tantalum containers. This compound features a unique polyanion structure with multicentered bonding, confirmed by EHMO calculations.

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