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Updated: Aug 14, 2026

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−
Published on: July 27, 2018
Vertical Ionization Energies and Electron Affinities of Ions in Solution from Outer-Sphere Charge Transfer Transition
S. I. Gorelsky1, V. Yu. Kotov, A. B. P. Lever
1Department of Chemistry, York University, Toronto, Ontario, Canada M3J 1P3.
Abstract:
Outer-sphere charge transfer (OSCT) transitions are shown to correlate with previously published photoelectron emission threshold energies. From these data it is possible to generate a set of parameters, I(D) and I(A), which define these OSCT energies, where I(D) is identified as the solution phase vertical ionization potential, and I(A) is the solution phase vertical electron affinity. An easy procedure for deriving these data for a wide variety of cations and anions is presented. The application of these data leads to a powerful procedure for extracting reorganization and solvation energies of value in a variety of applications.
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