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Covalent Three-Dimensional Titanium(IV)-Aryloxide Networks
Thomas P. Vaid1, Joseph M. Tanski, John M. Pette
1Cornell University, Baker Laboratory, Department of Chemistry & Chemical Biology, Ithaca, New York 14853.
Inorganic Chemistry
|October 24, 2001
Abstract:
Ti((i)OPr)(4) was treated with 2.58 equiv of hydroquinone in THF to yield a red-orange powder formulated as [Ti(OC(6)H(4)O)(a)()(OC(6)H(4)OH)(3.34)(-)(1.83)(a)()(O(i)Pr)(0.66)(-)(0.17)(a)() (THF)(0.2)](n)() (1, (0.91