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Total Synthesis of (+/-)-Sarracenin
Meng-Yang Chang1, Chi-Peng Chang, Wei-Kung Yin
1Department of Chemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan 804, Republic of China.
The Journal of Organic Chemistry
|February 7, 1997
Abstract:
A total synthesis of (+/-)-sarracenin (1) is described. The key steps include (1) regioselective ring expansion of 7 to bicyclo[3.2.1]ketone6 and (2) ring opening of tricyclic ketone 5 to ester 4.
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