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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
N-Cyclopropylimine-1-pyrroline rearrangement. A novel photochemical reaction
P J Campos1, A Soldevilla, D Sampedro
1Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, Unidad Asociada al C.S.I.C., Madre de Dios, 51, E-26006 Logroño, Spain. pedro.campos@dq.unirioja.es
Abstract:
[reaction: see text] A novel aza-(vinylcyclopropane-cyclopentene) photochemical rearrangement is reported. 1-Pyrrolines are easily synthesized in good yields from N-cyclopropylimines. Hydrogen, alkyl, and aryl groups can be placed anywhere within the system, and the reaction proceeds regiospecifically.
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