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[N-[dimethyl(eta5-2,3,4,6-tetramethylindenyl)silyl]cyclobutylamido-kappaN](eta4-1,4-diphenyl-1,3-buta-diene)titanium(
K A Abboud1, P N Nickias, E Y Chen
1Department of Chemistry, University of Florida, PO Box 117200, Gainesville, Florida 32611-7200, USA. abboud@ufl.edu
Acta Crystallographica. Section C, Crystal Structure Communications
|December 12, 2001
Abstract:
The titanium metal center in the title compound, [Ti(C19H27NSi)(C16H14)], is coordinated in a distorted tetrahedral geometry by a eta5-indenyl ligand, a dimethylsilyl-bridged N-cyclobutylamido ligand and an s-cis-eta4-1,4-diphenyl-1,3-butadiene ligand in a 'prone' pi-fashion, revealing a formal divalent Ti center.