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AgCo3PO4(HPO4)2
Abderrahmen Guesmi1, Ahmed Driss
1Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire, Tunis, Tunisia.
Acta Crystallographica. Section C, Crystal Structure Communications
|January 10, 2002
Abstract:
The structure of the hydrothermally synthesized compound AgCo3PO4(HPO4)2, silver tricobalt phosphate bis(hydrogen phosphate), consists of edge-sharing CoO6 chains linked together by the phosphate groups and hydrogen bonds. The three-dimensional framework delimits two types of tunnels which accommodate Ag+ cations and OH groups. The title compound is isostructural with the compounds AM3H2(XO4)3 (A = Na or Ag, M = Co or Mn, and X = P or As) of the alluaudite structure type.