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Related Concept Videos

Lewis Symbols and the Octet Rule02:36

Lewis Symbols and the Octet Rule

Chemical bonds are complex interactions between two or more atoms or ions, which reduce the potential energy of the molecule. Gilbert N. Lewis developed a model called the Lewis model that simplified the depiction of chemical bond formation and provided straightforward explanations for the chemical bonds seen in most common compounds.
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Lewis Structures and Formal Charges02:19

Lewis Structures and Formal Charges

Lewis symbols can be used to indicate the formation of covalent bonds, which are shown in Lewis structures—drawings that describe the bonding in molecules and polyatomic ions. The periodic table can be used to predict the number of valence electrons in an atom and the number of bonds that will be formed to reach an octet. Group 18 elements, such as argon and helium, have filled electron configurations and thus rarely participate in chemical bonding. However, atoms from group 17, such as bromine...
Structure of Alkanes02:23

Structure of Alkanes

The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.
Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes. 
Alkanes are the simplest hydrocarbons with sp3 hybrid carbon atoms. These sp3...
Structure and Bonding of Alkenes02:47

Structure and Bonding of Alkenes

Olefins, which are unsaturated hydrocarbons containing one or more carbon–carbon double bonds, are broadly divided into alkenes and cycloalkenes. The general chemical formula of an alkene is CnH2n.
Doubly bonded carbons are sp2 hybridized and have a trigonal planar geometry. The double bond is composed of a σ bond formed by the overlap of hybrid orbitals and a π bond produced by the lateral overlap of unhybridized 2p orbitals on both the carbons. Each carbon atom is bonded to two hydrogen atoms...
Structure of Benzene: Molecular Orbital Model01:18

Structure of Benzene: Molecular Orbital Model

According to the molecular orbital (MO) model, benzene has a planar structure with a regular hexagon of six sp2 hybridized carbons. As shown in Figure 1, each carbon is bonded to three other atoms with C–C–C and H–C–C bond angles of 120°. The C–H bond length is 109 pm, and the C–C bond length is 139 pm which is midway between the single bond length of sp3 hybridized carbons (154 pm) and sp2 hybridized carbons (133 pm).

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Mesostructured forms of gamma-Al(2)O(3).

Zhaorong Zhang1, Randall W Hicks, Thomas R Pauly

  • 1Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, Michigan 48824, USA.

Journal of the American Chemical Society
|February 21, 2002
PubMed
Summary

Researchers developed stable mesoporous gamma-alumina (MSU-gamma) with enhanced surface area and pore volume. These advanced materials improve catalytic efficiency in petroleum refining and emission control.

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Area of Science:

  • Materials Science
  • Catalysis
  • Nanotechnology

Background:

  • Gamma-alumina (γ-Al2O3) is a key material in heterogeneous catalysis.
  • Conventional γ-Al2O3 has limited surface area (<250 m²/g) and pore volume (<0.5 cm³/g).
  • Previous mesoporous alumina forms were structurally unstable with amorphous walls.

Purpose of the Study:

  • To synthesize structurally stable mesoporous gamma-alumina (MSU-gamma).
  • To achieve significantly higher surface area and pore volume compared to conventional forms.
  • To explore the potential of these materials in catalytic applications.

Main Methods:

  • Assembly of a mesostructured surfactant/boehmite precursor (MSU-S/B).
  • Hydrolysis of aluminum species in the presence of nonionic surfactants.
  • Characterization of the resulting mesoporous gamma-alumina structures.

Main Results:

  • Successfully prepared structurally stable mesoporous gamma-alumina (MSU-gamma).
  • Achieved surface areas up to 370 m²/g and pore volumes up to 1.5 cm³/g.
  • Demonstrated the formation of a stable mesostructured precursor.

Conclusions:

  • MSU-gamma represents a significant advancement in mesoporous alumina synthesis.
  • These materials possess properties suitable for enhancing catalytic processes.
  • Potential applications include petroleum refining, petrochemical processing, and automotive exhaust treatment.