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Barium tetraphosphate.

Jamal Bennazha¹, Ali Boukhari, Elizabeth M Holt

¹Département de Chimie, Faculté des Sciences et Techniques, Université Hassan-II, Mohammedia, Morocco.

Acta Crystallographica. Section C, Crystal Structure Communications

|March 1, 2002

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The low-temperature structure of barium tetraphosphate, Ba(3)P(4)O(13), reveals the tetraphosphate anion adopting an S conformation. This finding provides insight into the structural behavior of inorganic phosphate materials.

Area of Science:

Inorganic Chemistry
Solid-State Chemistry
Crystallography

Background:

Barium tetraphosphate (Ba(3)P(4)O(13)) is an inorganic compound with potential applications in materials science.
Understanding the structural properties of such compounds is crucial for predicting and controlling their behavior.

Purpose of the Study:

To determine the crystal structure of the low-temperature form of barium tetraphosphate.
To elucidate the specific conformation of the tetraphosphate anion in this crystalline phase.

Main Methods:

Single-crystal X-ray diffraction was employed to analyze the crystalline structure.
Detailed structural analysis was performed to identify bond lengths, angles, and overall molecular geometry.

Main Results:

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The crystal structure of Ba(3)P(4)O(13) at low temperatures was successfully determined.
The tetraphosphate anion ([P(4)O(13)](6-)) was found to adopt a distinct 'S' conformation.

Conclusions:

The 'S' conformation of the tetraphosphate anion in Ba(3)P(4)O(13) provides valuable structural information.
This detailed structural understanding contributes to the broader knowledge of polyphosphate chemistry and solid-state inorganic materials.