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Mechanochemical synthesis of a novel C(60) dimer connected by a silicon bridge and a single bond
Koichi Fujiwara1, Koichi Komatsu
1Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
Organic Letters
|March 15, 2002
Abstract:
[reaction: see text] A novel C(60) dimer connected by a silicon bridge and a single bond was synthesized by the mechanochemical solid-state reaction employing a high-speed vibration milling technique and fully characterized by the (1)H and (13)C NMR, APCI mass, and UV-vis spectroscopy. The presence of the electronic interaction between the two C(60) cages was demonstrated by the electrochemical method.