Experimental evidence of power-law trapping-time distributions in porous media

We present experimental results of solute transport in porous samples made of packings of activated carbon porous grains. Exchange experiments, where the tagged solution initially saturating the medium is replaced with the same solution without tracer, are accurately described by macroscopic transport equations. On the other hand, in desorption experiments, where the tagged solution is replaced by water, the solute concentration exhibits a power-law decay for long times, which requires a more detailed, mesoscopic description. We reproduce this behavior within a continuous-time random-walk approach, where the waiting time distribution is related to the desorption isotherm. Results are compatible with a power-law trapping time distribution with divergent first moment, characteristic of anomalous (sub)diffusion.