Related Experiment Video
Updated: Aug 15, 2026

High Resolution Phonon-assisted Quasi-resonance Fluorescence Spectroscopy
Published on: June 28, 2016
Zero loss peak deconvolution for bandgap EEL spectra
B Rafferty1, S J Pennycook, L M Brown
1Solid State Division, Oak Ridge National Laboratory, TN 37831-6030, USA. dr.rafferty@physics.org
Abstract:
This paper shows how bandgap EEL spectra are commonly processed either by deconvolution or subtraction methods in an attempt to remove effects arising from the finite width and long tail of the zero loss peak. This paper will compare the two main methods, and show that the deconvolution method is significantly more reliable and free of user-interpretation or artefacts. We first consider how the zero loss peak is produced and what effects experimental conditions have upon it, and then show that only by the deconvolution method can accurate bandgap energies and bandgap densities of states be determined.
Related Concept Videos
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)
IR Spectrum Peak Broadening: Hydrogen Bonding
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular hydrogen bonding...
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations
NMR Spectrometers: Resolution and Error Correction
¹³C NMR: ¹H–¹³C Decoupling
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
Double Resonance Techniques: Overview
Spin decoupling is usually achieved by...

