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Updated: Jul 8, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
[Au(2)Tl(2)(C(6)Cl(5))(4)].(CH(3))(2)C=O: a luminescent loosely bound butterfly cluster with a Tl(I)-Tl(I)
Eduardo J Fernández1, José M López-De-Luzuriaga, Miguel Monge
1Departamento de Química Inorgánica-ICMA, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain.
Abstract:
By reaction of NBu(4)[Au(C(6)Cl(5))(2)] with TlPF(6) in acetone the complex [Au(2)Tl(2)(C(6)Cl(5))(4)].(CH(3))(2)C=O is obtained, which shows a butterfly type arrangement of metals through short Au(I)-Tl(I) and Tl(I)-Tl(I) interactions. The last one is likely to be responsible for its luminescence behavior.
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