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Intrazeolite photooxidations of electron-poor alkenes
Edward L Clennan1, Jakub P Sram, Andrea Pace
1Department of Chemistry, University of Wyoming, Laramie, WY 82071, USA. clennane@uwyo.edu
The Journal of Organic Chemistry
|May 25, 2002
Abstract:
The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.