[Stability of HDTMA modified montmorillonite]
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Updated: Oct 1, 2026

Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate
Published on: February 23, 2016
Liuyan Yang1, Qiuqin Fu, Lijuan Jiang
1State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing, 210093, China. yangly@nju.edu.cn
Abstract:
In order to probe the stability of organic montmorillonite, the nature montmorillonite was modified with hexadeeyltrimethylammonium (HDTMA) in different cation exchange capacity (CEC). The results of experiments showed that the stability of modified montmorillonite declined as its CEC was big and HDTMA was desorbed from 1.0 CEC modified montmorillonite. HDTMA bound to the montmorillonite surface was resistant to temperature(70 degrees C) and instable to strong ultrasonic and to vibrational intensity(180 r/min). The result also indicated that the stability of modified montmorillonite increased to NaCl(1.8 mol/L) but decreased to CaCl2 (1.8 mol/L) and modified montmorillonite was more stable in high-pH environment(12.00) than in low-pH environment(2.06). On the basis of the results of these studies, low CEC modified montmorillonite appeared suitable as a sorbent for wastewater chemical treatment and as carrier for wastewater biotreatment in low stir environment.
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