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Silver-promoted reactions of bicyclo[3.2.1]octadiene derivatives
Ravi S Orugunty1, Dennis L Wright, Merle A Battiste
1Department of Chemistry, University of Florida, Gainesville, Florida 32606, USA.
Organic Letters
|June 7, 2002
Abstract:
[reaction: see text] Highly substituted bicyclo[3.2.1]octadiene building blocks are easily prepared from tetrachloro- or tetrabromocyclopropene through reaction with cyclic dienes. These polyhalogenated derivatives can serve as precursors to a variety of functionalized bridged bicyclic compounds. Herein, we report on the generation and reaction of electrophilic species with silver ion.