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Dilithium barium diphosphate.

Nezha Dridi1, E Arbib, Ali Boukhari

  • 1Laboratoire de Chimie du Solide Appliqué, Laboratoire Associé Francophone N degrees 501, Université Mohammed V, Agdal, Av. Ibn Batouta, BP 1014, Rabat, Morocco.

Acta Crystallographica. Section C, Crystal Structure Communications
|June 7, 2002
PubMed
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This study reveals the crystal structure of lithium barium diphosphate (Li(2)BaP(2)O(7)). Its unique 3D lattice features linked polyhedra and diphosphate groups, creating tunnels for lithium cations.

Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Materials science

Background:

  • Understanding novel diphosphate structures is crucial for materials development.
  • Lithium and barium compounds offer diverse properties.

Purpose of the Study:

  • To elucidate the crystal structure of the novel diphosphate, Li(2)BaP(2)O(7).
  • To characterize the atomic arrangement and bonding within the material.

Main Methods:

  • Single-crystal X-ray diffraction was used to determine the crystal structure.
  • Analysis of polyhedral linkages and cation coordination.

Main Results:

  • Li(2)BaP(2)O(7) exhibits a three-dimensional lattice.
  • The structure comprises BaO(9) polyhedra and P(2)O(7) diphosphate groups.

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  • Layers are formed parallel to the (010) plane, interconnected by P-O-Ba bridges.
  • Tunnels within the lattice are occupied by Li(+) cations.

    • Conclusions:

    • The determined crystal structure provides fundamental insights into lithium barium diphosphate.
    • The unique structural features, including tunnels and cation positions, may influence material properties.