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Polymeric bis(N,N-dimethylacetamide)tetrakis(thiocyanato)cadmium(II)mercury(II)
Xin Qiang Wang1, Wen Tao Yu, Dong Xu
1State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China. xqwang@icm.sdu.edu.cn
Abstract:
The title complex, [[CdHg(SCN)(4)(C(4)H(9)NO)(2)](2)](n), contains two crystallographically independent Cd(II) centres and two Hg(II) centres. Each Cd(II) atom is bound to four N atoms belonging to SCN groups and to two O atoms from N,N-dimethylacetamide (DMA) ligands in an octahedral geometry. Each Hg(II) centre is tetrahedrally coordinated by four SCN S atoms.