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An unprecedented example of a cis-phosphonodithioato nickel(II) complex built by an extensive hydrogen bonding
Vincenzo G Albano1, M Carla Aragoni, Massimiliano Arca
1Dipartimento di Chimica G. Ciamician, Via Selmi 2, I-40126 Bologna, Italy.
Chemical Communications (Cambridge, England)
|July 12, 2002
Abstract:
The P-N bond hydrolysis of the 4-methoxyphenyl-ammonium ethylamido-phosphonodithioato ligand during its complexation to NiII leads to the first example of phosphonodithioato nickel(II) complex having a cis configuration; this complex is stabilised in the solid state by an extensive and intricate network of hydrogen bondings involving the released ethylenediamine and a water molecule.