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Synthesis and crystal structure of the first scandium-containing open framework solid
Ivor Bull1, Paul S Wheatley, Philip Lightfoot
1School of Chemistry, University of St Andrews, St Andrews, Fife, UK KY16 9ST.
Chemical Communications (Cambridge, England)
|July 12, 2002
Abstract:
A novel open framework scandium sulfate phosphate is prepared hydrothermally in the presence of the azamacrocycle cyclen (1,4,7,10-tetraazacyclododecane) in which secondary building units of formula Sc7(S,P)12O48 are linked to give a structure with supercages.