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Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation
Takeshi Maeda1, Yoshio Furusho, Toshikazu Takata
1Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, Japan.
Chirality
|July 12, 2002
Abstract:
Poly(binaphthyl salen manganese complex)es 3-Mn were synthesized from a 3,3'-diformylbinaphthol derivative, alpha,omega-diamines, and Mn(OAc)2. Their helical structures were well-supported by their IR, UV, and CD spectra. The catalysis of 3-Mn in an asymmetric epoxidation was investigated.