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Monoalkyl, chiral-at-metal 'constrained geometry' complexes as efficient alpha-olefin and methyl methacrylate
Jizhu Jin1, David R Wilson, Eugene Y X Chen
1Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
A new class of monoalkyl or monochloro constrained geometry group 4 complexes has been synthesized; upon activation with aluminium activators they serve as efficient catalysts for olefin polymerisation and for polymerisation of methyl methacrylate.