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Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand
Edward J Farrington1, Eloisa Martinez Viviente, B Scott Williams
1Dyson Perrins Laboratory, South Parks Road, Oxford, UK OX1 3QY.
Chemical Communications (Cambridge, England)
|July 18, 2002
Abstract:
The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C-H insertion into the ferrocene.