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Updated: Sep 30, 2026
![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Synthesis, crystal and molecular structure of [Sn(eta 4-P2C2But2)]: the first non transition metal
Matthew D Francis1, Peter B Hitchcock
1School of Chemistry, Physics and Environmental Science, University of Sussex, Brighton, UK BN1 9QJ. m.d.francis@sussex.ac.uk
Abstract:
Treatment of [Zr(eta 5-C5H5)2(PCBut)2] with SnCl2 led to the novel monomeric (1,3-diphosphacyclobutadienyl)tin(II) half sandwich complex [Sn(eta 4-P2C2But2)] which has been characterised by multinuclear NMR spectroscopy and in the solid state by a single crystal X-ray diffraction study.
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