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A novel [60]fullerene receptor with a Pd(II)-switched bisporphyrin cleft
Masatsugu Ayabe1, Atsushi Ikeda, Seiji Shinkai
1Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812-8581, Japan.
Abstract:
Porphyrin dimer 1, which does not have an inside cavity and cannot interact with [60]fullerene (C60), becomes an excellent C60-acceptor with a large cavity in the presence of a Pd(II) complex.