Related Experiment Video
Updated: Sep 30, 2026
Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods
Published on: October 6, 2023
Two chain gallium fluorodiphosphates: synthesis, structure solution, and their transient presence during the
Franck Millange1, Richard I Walton, Nathalie Guillou
1Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035, Versailles, France. millange@chimie.uvsq.fr
Abstract:
Two novel gallium fluorodiphosphates have been isolated and their structures solved ab initio from powder X-ray diffraction data; the materials readily interconvert under hydrothermal conditions, and are metastable with respect to an open-framework zeolitic gallium fluorophosphate, during the synthesis of which they are present as transient intermediates.
