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Intramolecular radical hydrosilylation--the first radical 5-endo-dig cyclisation
Stephan Amrein1, Armido Studer
1Fachbereich Chemie der Universität Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany.
Abstract:
Intramolecular radical hydrosilylations using allyloxy- and propargyloxycyclohexadienylsilanes comprising 5-endo-trig as well as 5-endo-dig processes are presented.