A sonotrode for electroanalysis: the determination of copper in passivating media

A sonotrode consisting of a disc shaped glassy carbon electrode attached to a quartz rod and inserted into a drilled ultrasonic probe tip has been designed and used as a novel alternative to the traditional 'face on' cell arrangement where an ultrasonic micro-tip probe is placed opposite a glassy carbon working electrode. The 'single probe' arrangement is both convenient and optimised for electroanalysis. We first report how under ultrasonic agitation of the sonotrode the mass transport to the electrode surface is enhanced compared to that observed under silent conditions and also how the sonotrode cell geometry compares with the well-established 'face on' cell geometry for cobalt electrodeposition. Second, we will show that the new sonotrode can be used in the application for the determination of copper in a series of fouling media in which conventional silent electroanalysis fails. The passivation of the electrodes surface by surfactant species can be overcome by cavitationally induced streaming and/or erosion at the sonotrode surface with recoveries of 100% and 93.8% achieved at 42 W cm-2 for Triton X-100 and sodium dodecyl sulfate (SDS), respectively. Other data indicates that the sonotrode can be successfully employed for the detection of copper in beer (Marston's bitter), a system known to be complex and highly electrode fouling and difficult to analyse using standard, silent electroanalytical techniques.