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Empirical model for the molar rotations of syn-2,2-dimethyl-1,3-dioxanes
Christopher D Anderson1, Scott D Rychnovsky
1Department of Chemistry, 516 Rowland Hall, University of California-Irvine, 92697-2025, USA.
Organic Letters
|August 31, 2002
Abstract:
[structure: see text] A useful method for the prediction of molar rotation ([Phi]) of syn-2,2-dimethyl-1,3-dioxanes (acetonides) is described. A series of acetonides were prepared by standard methods. A simple additive relationship between the substituents (R, R') and molar rotation was realized.