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Synthesis of the dibismuthene complex [[micro-eta2-(cis-Me(3)SiCH(2)Bi)(2)][W(CO)(5)](2)] from a cyclobismuthane and

Lucia Balázs1, Hans Joachim Breunig, Enno Lork

  • 1Universität Bremen Institut für Anorganische und Physikalische Chemie 28334 Bremen, Germany.

Angewandte Chemie (International Ed. in English)
|August 31, 2002
PubMed
Abstract

No abstract available in PubMed .

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
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Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...

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