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Updated: Sep 17, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Synthesis, complexation, and supramolecular assembly of 21,30-dithia-17,25-dimethyl-1,4,7,10,13-
1Department of Chemistry, National University of Singapore, Republic of Singapore 117543.
Abstract:
[structure: see text] A crownophane consisting of a dithia[3.3]metacyclophane moiety was synthesized by employing a high dilution method. The crystal structure and complexation behavior of this crownophane was studied. A hydrogen-bonded linear supramolecular assembly using anion-Na(+)-crownophane-solvent as a synthon was observed in the solid state. This supramolecular assembly was also stabilized via an intermolecular S.H-C interaction.
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