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Survival and extinction of delocalized ring currents in clamped benzenes
P W Fowler1, R W Havenith, L W Jenneskens
1School of Chemistry, University of Exeter, Stocker Road, Exeter, UK EX4 4QD. P.W.Fowler@exeter.ac.uk
Abstract:
Direct visualisation of induced current density in clamped benzenes 1-4 distinguishes between saturated clamping groups, for which the central benzene ring retains a conventional diamagnetic ring current, and strongly interacting, unsaturated clamps, for which the central ring supports only the localised circulations expected of a 1,3,5-cyclohexatriene with fully fixed double bonds.