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A novel intramolecular through-space interaction between F and CN: a strategy for the conformational control of an
K Nishide1, Y Hagimoto, H Hasegawa
1Department of Pharmaceutical Manufacturing Chemistry, Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 607-8414, Japan.
Chemical Communications (Cambridge, England)
|September 21, 2002
Abstract:
X-Ray crystallographic analyses of fluorocyanides anti-1 and 2 revealed a novel intramolecular through-space interaction between F and CN in an acyclic system, which was applied to a stereoselective protonation of acyclic fluorocyanides 2 having flexible conformation.