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Highly effective epoxidation of alkenes with Ti-containing soluble polymers
G Blanco-Brieva1, J M Campos-Martín, M P de Frutos
1Instituto de Catálisis y Petroleoquímicaa, CSIC, Campus Cantoblanco, 28049 Madrid, Spain.
Chemical Communications (Cambridge, England)
|September 21, 2002
Abstract:
Ti-containing polysiloxane epoxidation catalysts have been prepared by controlled hydrolysis of titanium- and alkylsilane precursors. These polysilkoxanes exhibit very high yields to epoxides in the epoxidation reaction of primary alkenes with organic hydroproxides.