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Mesopore immobilised copper bis(oxazoline) complexes for enantioselective catalysis
1School of Chemical Sciences, University of Birmingham, Birmingham, UK B15 2TT.
Abstract:
New supported heterogeneous catalysts have been synthesised through the tethering of copper bis(oxazoline) complexes to the surfaces of MCM-41 and MCM-48 mesoporous materials, and the prepared catalysts shown to be highly active in the enantioselective cyclopropanation of styrene with ethyl diazoacetate.