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Tetrathiafulvalene-acetylene scaffolding: new pi-electron systems for advanced materials
M B Nielsen1, N N Moonen, C Boudon
1Laboratorium für Organische Chemie, ETH-Zentrum, Universitätstrasse 16, CH-8092 Zürich, Switzerland.
Abstract:
Novel extended tetrathiafulvalenes (TTFs) with hexa-2,4-diyne-1,6-diylidene spacers between the two 1,3-dithiole rings and laterally appended alkynyl moieties for one- and two-dimensional scaffolding were synthesised and investigated for their electronic properties.