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A pi-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)(ClC2NS2)
Leanne Beer1, A Wallace Cordes, Robert C Haddon
1Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.
Abstract:
Crystals of (Cl2C3NS)(ClC2NS2), an isothiazolyl-substituted 1,2,3-dithiazolyl radical, consist of evenly spaced, slipped pi-stacks; magnetic and conductivity measurements indicate the material is a Mott insulator with sigma RT = 2 x 10(-7) S cm-1.