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Controlled monomer insertion into polymer main chain: synthesis of sequence ordered polystyrene containing
Suguru Motokucho1, Atsushi Sudo, Fumio Sanda
1Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan.
Abstract:
A polymer having a trithiocarbonate moiety in the main chain was applied as a polymeric precursor to the synthesis of a sequence ordered polymer by insertion polymerization of styrene into the main chain by a RAFT mechanism.