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Syntheses and structures of structurally diverse potassium beta-diketiminates derived from the ligand
Peter B Hitchcock1, Michael F Lappert, Diang-Sheng Liu
1Chemistry Laboratory, University of Sussex, Brighton, UK BN1 9QJ.
Chemical Communications (Cambridge, England)
|September 28, 2002
Abstract:
The compounds [K((mu-N(SiMe3)C(Ph))2CH)(thf)2]infinity 1, [K(mu-N(SiMe3)C(Ph)C(H)C(Ph)NH)L]2 [L = (thf)2 2, tmen 3], [K(mu-NSi(Me)2C(Ph)C(H)C(Ph)N)(thf)3]2 4 and [K(N(H)C(Ph))2CH](thf)0.5 5 have been prepared from K[(N(SiMe3)C(Ph))2CH] and the X-ray structures of 1-4 are reported.