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Sidewall functionalization of single-walled carbon nanotubes through electrophilic addition
Nikos Tagmatarchis1, Vasilios Georgakilas, Maurizio Prato
1Nagoya University, Department of Chemistry, Nagoya 464-8602, Japan.
Abstract:
Electrophilic addition of chloroform to SWNTs followed by hydrolysis resulted in the addition of hydroxy groups to the surface of the nanotubes; further esterification with propionyl chloride led to the corresponding ester derivatives, which allowed us to identify their structure, also providing better solubility in organic solvents.