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In-situ analysis of stepwise self-assembled 1,6-hexanedithiol multilayers by surface plasmon resonance measurements
Soonwoo Chah1, Janos H Fendler, Jongheop Yi
1School of Chemical Engineering, Seoul National University, San 56-1, Shinlim, Kwanak, Seoul 151-742, Korea. swchah@hanmir.com
Abstract:
1,6-Hexandithiol (HDT) forms 6.9 +/- 1.0 A thick defect-free monolayers on gold substrates if the solution is purged by argon during the adsorption while long term (> 1000 min) exposure of the substrate to alcoholic HDT results in the stepwise formation of multilayers in the absence of argon purging.