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The first uranyl-methine carbon bond; a complex with out-of-plane uranyl equatorial coordination
Mark J Sarsfield1, Madeleine Helliwell, David Collison
1Centre for Radiochemistry Research, Department of Chemistry, University of Manchester, Manchester, UK M13 9PL. mark.j.sarsfield@man.ac.uk
Chemical Communications (Cambridge, England)
|October 26, 2002
Abstract:
Treatment of [UO2Cl2(thf)3] in thf with one equivalent of [Na(CH(Ph2P = NSiMe3)2)] yields an unusual uranyl chloro-bridged dimer containing a uranium(VI)-carbon bond as part of a tridentate bis(iminophosphorano)methanide chelate complex. The methine carbon is displaced significantly from the uranyl equatorial plane.