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Cluster persistence in one-dimensional diffusion-limited cluster-cluster aggregation.

E K O Hellén1, P E Salmi, M J Alava

  • 1Laboratory of Physics, Helsinki University of Technology, P. O. Box 1100, FIN-02150 HUT, Finland. ehe@fyslab.hut.fi

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|January 7, 2003
PubMed
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We studied how cluster persistence probability changes with cluster size in aggregation. For negative exponents, spatial fluctuations are crucial, impacting persistence and cluster size distribution.

Area of Science:

  • Physics
  • Statistical Mechanics
  • Complex Systems

Background:

  • Cluster-cluster aggregation is a fundamental process in various physical and chemical systems.
  • Understanding cluster persistence is key to predicting system evolution and final structures.
  • The diffusion coefficient's size dependence (D(s) ~ s^gamma) significantly influences aggregation dynamics.

Purpose of the Study:

  • To investigate the persistence probability P(C)(t) in cluster-cluster aggregation.
  • To analyze the impact of diffusion coefficient's size dependence (D(s) ~ s^gamma) on aggregation.
  • To determine the relationship between persistence and cluster size distribution.

Main Methods:

  • Mapping the problem to the survival of three annihilating random walkers with time-dependent noise correlations in the mean-field limit.

Related Experiment Videos

  • Analyzing the behavior of persistence probability for different values of the exponent gamma.
  • Investigating the influence of spatial fluctuations on the system for gamma < 0.
  • Main Results:

    • For gamma >= 0, mean-field theory accurately describes cluster persistence.
    • For gamma < 0, spatial fluctuations become relevant, leading to an overestimation of persistence by random walk theory.
    • The decay of persistence dictates the small-size tail of the cluster size distribution.
    • For 0 < gamma < 2, the cluster size distribution is surprisingly flat and independent of gamma.

    Conclusions:

    • The exponent gamma critically determines the relevance of mean-field theory versus spatial fluctuations in cluster aggregation.
    • Spatial fluctuations play a significant role for negative gamma, affecting persistence and size distribution.
    • The study provides insights into the universality of cluster size distributions in aggregation processes.