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Ligand-accelerated cadmium-catalyzed asymmetric allylation reactions in aqueous media
Shū Kobayashi1, Naohiro Aoyama, Kei Manabe
1Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. skobayas@mol.f.u-tokyo.ac.jp
Chirality
|January 10, 2003
Abstract:
Catalytic asymmetric allylation of aldehydes with allyltributyltin in aqueous media has been realized using combinations of cadmium bromide and chiral diamine ligands. These ligands were found to accelerate the reactions significantly.