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A novel dicationic phenoxaphosphino-modified xantphos-type ligand--a unique ligand specifically designed for a high
Raymond P J Bronger1, Silvana M Silva, Paul C J Kamer
1Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Chemical Communications (Cambridge, England)
|January 23, 2003
Abstract:
A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments.