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Asymmetric synthesis of the putative structure of (-)-oryzoxymycin
Mark E Bunnage1, Thota Ganesh, Ishmael B Masesane
1Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK.
Organic Letters
|January 31, 2003
Abstract:
[reaction: see text] A short asymmetric synthesis of (2'S,5R,6R)-2'-[6-amino-5-hydroxy-1,3-cyclohexadiene-1-carbonyloxy]propionic acid, the enantiomer of the reported structure of (+)-oryzoxymycin is described. The reported spectral data does not match that obtained for synthetic "oryzoxymycin".